Hazardous chemicals placard and manifest quantities

This bulletin provides information on the placard and manifest quantities of hazardous chemicals, as specified in Schedule 11 of the Work Health and Safety (National Uniform Legislation) Regulations 2011 (the Regulations). The final column of this table shows the link between the Globally Harmonised System of Classification (GHS) classes and categories and the equivalent classes and categories of dangerous goods under the Australian Dangerous Goods Code (ADG).

Note: Where Schedule 13 of the Regulations requires a placard, the relevant dangerous goods class label (pictogram) must be displayed on the placard, rather than the corresponding GHS pictogram.

Column 1 Column 2 Column 3 Column 4 Column 5
Item Description of hazardous chemical Placard quantity Manifest quantity ADG Code Classification
Hazard class Hazard Category
1. Flammable gases Category 1 200L 5000L 2.1
2. Gases under pressure with acute toxicity, categories 1, 2, 3 or 4
Note: Category 4 only up to LC50 of 5000 ppmV
50L 500L 2.3
3. with skin corrosion categories 1A, 1B or 1C 50L 500L 2.3
4. aerosols 5000L 10 000L 2.1 or 2.2
5. not specified elsewhere in this Table 1000L 10 000L 2.2
6. Flammable liquids Category 1 50L 500L 3 (PG I)
7. Category 2 250L 2500L 3 (PG II)
8. Category 3 1000L 10 000L 3 (PG III)
9. Any mix of chemicals from Items 6-8 where none of the items exceeds the quantities in columns 4 or 5 on their own.1000L10 000L 
10.Category 410 000L100 000LNote 3
11.Self-reactive substancesType A5kg or 5L50kg or 50LGTDTBT - Note 4
12.Type B50kg or 50L500kg or 500L4.1 (Type B)
13.Type C-F250kg or 250L2500kg or 2500L4.1 (Type C-F)
14.Flammable solidsCategory 1250kg2500kg4.1 (PG II)
15.Category 21000kg10 000kg4.1 (PG II)
16. Any mix of chemicals from items 12-15 where none of the items exceeds the quantities in columns 4 or 5 on their own. 1000kg or 1000L10 000kg or
10 000L
 
17.Pyrophoric liquids and Pyrophoric solidsCategory 150kg or 50L500kg or 500L4.2 (PG I)
18.Self heating substances and mixturesCategory 1250kg or 250L2500kg or 2500L4.2 (PG II)
19.Category 21000kg or 1000L10 000kg or
10 000L 
4.2 (PG III)
20. Any mix of chemicals from Items 17 - 19 where none of the items exceeds the quantities in columns 4 or 5 on their own1000kg or 1000L10 000kg or
10 000L
 
21.Substances which in contact with water emit flammable gasCategory 150kg or 50L500kg or 500L4.3 (PG I)
22.Category 2250kg or 250L2500kg or 2500L4.3 (PG II)
23.Category 31000kg or 1000L10 000kg or
10 000L 
4.3 (PG III)
24.Any mix of chemicals from Items 21 - 23 where none of the items exceeds the quantities in columns 4 or 5 on their own1000kg or 1000L10 000kg or
10 000L 
 
25.Oxidising liquids and Oxidising solidsCategory 150kg or 50L500kg or 500L5.1 (PG I)
26. Category 2250kg or 250L2500kg or 2500L5.1 (PG II)
27. Category 31000kg or 1000L10 000kg or
10 000L 
5.1 (PG III)
28. Any mix of chemicals from Items 25-27 where none of the items exceeds the quantities in columns 4 or 5 on their own1000kg or 1000L10 000kg or
10 000L
 
29.Organic peroxidesType A5kg or 5L50kg or 50LGTDTBT - Note 4
30.Type B50kg or 50L500kg or 500L5.2 (Type B)
31.Type C-F250kg or 250L2500kg or 2500L5.2 (Type C-F)
32.Any mix of chemicals from Items 30 and 31 where none of the items exceeds the quantities in columns 4 or 5 on their own250kg or 250L2500kg or 2500L 
33.Acute ToxicityCategory 150kg or 50L500kg or 500L6.1 (PG I) - Note 5
34.Category 2250kg or 250L2500kg or 2500L6.1 (PG II)
35.Category 31000kg or 1000L10 000kg or
10 000L
6.1 (PG III)
36. Any mix of chemicals from Items 33-35 where none of the items exceeds the quantities in columns 4 or 5 on their own1000kg or 1000L10 000kg or
10 000L
 
37.Skin corrosionCategory 1A50kg or 50L500kg or 500L8 (PG I)
38.Category 1B250kg or 250L2500kg or 2500L8 (PG II)
39.Category 1C1000kg or 1000L10 000kg or
10 000L
8 (PG III)
40.Corrosive to metalsCategory 11000kg or 1000L10 000kg or
10 000L
8 (PG III)
41. Any mix of chemicals from Items 37-40 where none of the items exceeds the quantities in columns 4 or 5 on their own1000kg or 1000L10 000kg or
10 000L
 
42.Unstable explosives 5kg or 5L50kg or 50LGTDTBT - Note 4
43. Any mix of chemicals from Items 11, 29 and 42 where none of the items exceeds the quantities in columns 4 or 5 on their own5kg or 5L50kg or 50L 

Notes

  1. For the purposes of this table, if a flammable liquid category 4 is used, handled or stored in the same spill compound as one or more flammable liquids of categories 1, 2 or 3, the total quantity of flammable liquids categories 1, 2 or 3 must be determined as if the flammable liquid category 4 had the same classification as the flammable liquid in the spill compound with the lowest flash point.

    Example: For placard and manifest purposes, a spill compound containing 1000L of flammable liquid category 1 and 1000L of flammable liquid category 4 is considered to contain 2000L of flammable liquid category 1.

  2. For the item 2 in the table, Gases under pressure with acute toxicity category 4 only applies up to a LC50 of 5000 ppmV.  This is equivalent to Division 2.3 dangerous goods under the ADG Code.
  3. Only flammable liquids with a flash point of up to 93°C are classified as hazardous chemicals under the Work Health and Safety (National Uniform Legislation) Regulations 2011 and the GHS.  C1 combustible liquids with flashpoints between 93°C and 150°C are not classified as hazardous workplace chemicals.
  4. GTDTBT means goods too dangerous to be transported.
  5. Division 2.3 under the ADG Code includes gases and vapours classified as acutely toxic (categories 1, 2 and 3) and gases which are corrosive to skin (category 1).

Further information

Codes of Practice

Labelling of workplace hazardous chemicals

Preparation of safety data sheets for hazardous chemicals

Forms

Notification of schedule 11 hazardous chemicals

Guides

Schedule 11 hazardous chemicals and abandonment of tanks notifications

Manifest requirements for hazardous chemicals